1254173-25-5

Basic information

• Product Name: psiguadial A
• Synonyms: psiguadial A
• CAS NO: 1254173-25-5
• Molecular Weight: 474.597
• Mol File: 1254173-25-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: psiguadial A(CAS DataBase Reference)
• NIST Chemistry Reference: psiguadial A(1254173-25-5)
• EPA Substance Registry System: psiguadial A(1254173-25-5)

Safety Data

• Hazardous Substances Data: 1254173-25-5(Hazardous Substances Data)

Upstream product

• 32543-79-6 (1S,3R)-2,2-dimethyl-3-(3-oxobutyl)cyclopropane-1-carbaldehyde 
• 4497-92-1 2-carene 
• 4396-13-8 2,4-diformyl 2,4,6-trihydroxybenzene 
• 41437-00-7 (+)-bicyclogermacrene 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Biomimetic synthesis of (+)-ledene, (+)-viridiflorol, (-)-palustrol, (+)-spathulenol, and psiguadial A, C, and D via the platform terpene (+)-bicyclogermacrene

(+)-Bicyclogermacrene is a strained bicyclic and common sesquiterpene found in several essential oils. A short and good yielding synthesis of bicyclogermacrene proceeding in seven steps is reported. This terpene is used as key platform intermediate for a biomimetic access to several aromadendrene sesquiterpenoids, such as ledene, viridiflorol, palestrol, and spathulenol. Furthermore, bicyclogermacrene is shown to be the terpene component in the synthesis of the meroterpenoids psiguadial A, C, and D. Let nature be your guide! A concise synthesis of the terpene (+)-bicyclogermacrene enables its use as a platform for a fast access to a range of different terpenoids of the aromadendrene family and meroterpenoids of the psiguadial family (see scheme).