125443-73-4Relevant articles and documents
ASYMMETRIC SYNTHESIS VII: DOUBLE STEREODIFFERENTATION IN ALLYLYTION OF KETIMINES BEARING TWO CHIRAL AUXILIARIES. APPLICATION TO ENANTIOSELECTIVE SYNTHESIS OF α-ALLYLGLYCINE
Yaozhong, Jiang,Changyou, Zhou,Huri, Piao
, p. 881 - 888 (2007/10/02)
A diuble asymmetric induction has been observed in allylation of the imines derived from (+)-camphor, (+)- and (-)-2-hydroxypinan-3-ones with (+)- and (-)-menthyl glycinates.After hydrolysis of the allylated intermediates, (R)- and (S)-α-allylglycines are obtained in 3-90percent optical yields.