125453-11-4

Basic information

• Product Name: benzyl (1H-benzo[d][1,2,3]triazol-1-yl)methylcarbamate
• Synonyms: benzyl (1H-benzo[d][1,2,3]triazol-1-yl)methylcarbamate
• CAS NO: 125453-11-4
• Molecular Weight: 282.302
• Mol File: 125453-11-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: benzyl (1H-benzo[d][1,2,3]triazol-1-yl)methylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl (1H-benzo[d][1,2,3]triazol-1-yl)methylcarbamate(125453-11-4)
• EPA Substance Registry System: benzyl (1H-benzo[d][1,2,3]triazol-1-yl)methylcarbamate(125453-11-4)

Safety Data

• Hazardous Substances Data: 125453-11-4(Hazardous Substances Data)

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 50-00-0 formaldehyd 
• 621-84-1 O-benzyl carbamate 

Downstream Products

• 77943-39-6 4-methyl-5-phenyloxazolidin-2-one 
• 202932-27-2 [(R)-2-(4-Benzyloxy-phenyl)-3-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-3-oxo-propyl]-carbamic acid benzyl ester 
• 202932-28-3 3-[(R)-1-(Benzyloxycarbonylamino-methyl)-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-indole-1-carboxylic acid benzyl ester 
• 1202639-31-3 (+/-)-(4-Oxo-2-pyrimidin-4-yl-6,7,8,9-tetrahydro-4H-pyrido[1,2-a]pyrimidin-9-ylmethyl)-carbamic acid benzyl ester 
• 202932-34-1 (R)-3-Benzyloxycarbonylamino-2-(4-benzyloxy-phenyl)-propionic acid 
• 18605-26-0 3-(((benzyloxy)carbonyl)amino)propionic tert-butyl ester 
• 16251-45-9 (4S,5R)-4-methyl-5-phenyl-oxazolidin-2-one 
• 161583-20-6 [(R)-3-((4S,5R)-4-Methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-3-oxo-2-phenyl-propyl]-carbamic acid benzyl ester 
• 125453-30-7 Aminomethyl-carbamic acid benzyl ester 
• 3589-41-1 phenylmethyl cyanomethylcarbamate 
• 447420-69-1 di-tert-butyl 2-({[(benzyloxy)carbonyl]amino}methyl)malonate 

Relevant articles and documents

Convenient preparation of tert-butyl β-(protected amino)esters

Refluxing an aldehyde 1 with benzotriazole and benzylcarbamate in the presence of a catalytic amount of p-TsOH gave the corresponding benzyloxycarbonylamino-1-(1-benzotriazolyl)alkane 2 in good yields. Compounds 2 treated with substituted tert-butyl acetates 3 using LDA as a base afford smoothly and under mild conditions the N-2-protected 3-aminoalkanoic esters 4.