1256156-75-8

Basic information

• Product Name: 1-(2-iodophenyl)-1H-benzo[d][1,2,3]triazole
• Synonyms: 1-(2-iodophenyl)-1H-benzo[d][1,2,3]triazole
• CAS NO: 1256156-75-8
• Molecular Weight: 321.12
• Mol File: 1256156-75-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(2-iodophenyl)-1H-benzo[d][1,2,3]triazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-iodophenyl)-1H-benzo[d][1,2,3]triazole(1256156-75-8)
• EPA Substance Registry System: 1-(2-iodophenyl)-1H-benzo[d][1,2,3]triazole(1256156-75-8)

Safety Data

• Hazardous Substances Data: 1256156-75-8(Hazardous Substances Data)

Upstream product

• 100-68-5 methyl-phenyl-thioether 
• 95-14-7 1,2,3-Benzotriazole 
• 348-52-7 1-Fluoro-2-iodobenzene 
• 883-39-6 1-phenyl-1H-benzotriazole 
• 591-50-4 iodobenzene 
• 70551-64-3 1,3-bis(2-iodophenyl)triazene 
• 1256156-74-7 C₁₂H₉BrIN₃ 

Relevant articles and documents

N-Heterocycle-Stabilized Iodanes: From Structure to Reactivity

Pseudocyclic aryl-λ3-iodanes are superior reagents for a variety of oxidative transformations due to a well-balanced relation between stability, solubility and reactivity. Their properties are substantially influenced by a dative interaction between a Lewis base, in general the oxygen atom of a carboxylic acid or an amide, and the central hypervalent iodine atom. This work presents the first systematic investigation of pseudocyclic N-heterocycle-stabilized iodanes (NHIs). The synthesis of these throughout shelf-stable solids is robust and can be achieved on a large scale. Their reactivity is highly tunable, depending on the stabilizing heterocycle. Solid state structures of selected derivatives are reported and their reactivity in a model oxygen transfer reaction is compared. Further derivatization reactions to N-heterocycle-stabilized pseudocyclic diaryliodonium salts and cyclic iodoso species are presented as well.

A ligand-free copper (1) catalysed intramolecular N-arylation of diazoaminobenzenes in PEG-water: An expeditious protocol towards regiospecific 1-aryl benzotriazoles

An efficient and highly versatile method for the synthesis of diverse regiospecific 1-arylbenzotriazoles being important medicinal scaffolds, by the copper (1) catalysed intramolecular N-arylation of diazoaminobenzenes of 2-haloaryldiazonium salts in PEG-water has been developed. A very simple reaction protocol, large number of substrate affordability and excellent yields are the main features of this methodology.