1256262-90-4Relevant articles and documents
Synthesis of Oxatricyclooctanes via Photoinduced Intramolecular Oxa-[4+2] Cycloaddition of Substituted o-Divinylbenzenes
Liu, Qiang,Wang, Junlei,Li, Dazhi,Gao, Guo-Lin,Yang, Chao,Gao, Yuan,Xia, Wujiong
, p. 7856 - 7868 (2017/08/14)
The photolysis of substituted o-divinylbenzenes promotes a one-step and metal-free conversion to oxatricycles at room temperature. Irradiation o-divinylbenzenes results in an pericyclic reaction to form cyclic o-quinodiemthane intermediates, which subsequently undergo intramolecular oxa-[4+2] cycloaddition to form oxacyclic derivatives.
Synthesis of nonsymmetric divinylarenes by a heck/wittig reaction combination
Burmester, Christian,Mataka, Shuntaro,Thiemann, Thies
experimental part, p. 3196 - 3208 (2010/12/24)
A protocol for a one-pot Heck reaction/Wittig olefination to divinylarenes has been developed. Copyright Taylor & Francis Group, LLC.