1256285-01-4

Basic information

• Product Name: 2-(8,9-dimethyl-2,3,4,9-tetrahydro-1H-carbazol-4-yl)-1-p-tolylethanone
• CAS NO: 1256285-01-4
• Molecular Weight: 331.458
• Mol File: 1256285-01-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(8,9-dimethyl-2,3,4,9-tetrahydro-1H-carbazol-4-yl)-1-p-tolylethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(8,9-dimethyl-2,3,4,9-tetrahydro-1H-carbazol-4-yl)-1-p-tolylethanone(1256285-01-4)
• EPA Substance Registry System: 2-(8,9-dimethyl-2,3,4,9-tetrahydro-1H-carbazol-4-yl)-1-p-tolylethanone(1256285-01-4)

Safety Data

• Hazardous Substances Data: 1256285-01-4(Hazardous Substances Data)

Upstream product

• 1777-53-3 1-(p-tolyl)-2-(triphenylphosphoranylidene)ethanone 
• 619-41-0 4-(bromoacetyl)toluene 
• 122-00-9 para-methylacetophenone 
• 2689-61-4 (2-oxo-2-p-tolylethyl)triphenylphosphonium bromide 
• 1014623-84-7 1,7-dimethyl-2-(4-pentenyl)-1H-indole 
• 19832-78-1 1-(4-methylphenyl)prop-2-en-1-one 

Relevant articles and documents

Highly efficient route to functionalized tetrahydrocarbazoles using a tandem cross-metathesis/intramolecular-hydroarylation sequence

The scope of the novel ruthenium-catalyzed tandem cross-metathesis/ intramolecular-hydroarylation sequence is described. This methodology offers a practical and efficient synthesis of structurally diverse and complex tetrahydrocarbazoles in good to excellent yields (up to 98%). Moreover, preliminary efforts towards the development of an enantioselective version of the current process by sequential catalysis with ruthenium complex and chiral amine are presented, with high yields and enantioselectivities (up to 88% yield and 91% ee).