125653-69-2

Basic information

• Product Name: Benzenemethanol, a-methyl-4-(2-methylpropyl)-, acetate, (R)-
• CAS NO: 125653-69-2
• Molecular Formula: C14H20O2
• Molecular Weight: 220.312
• Mol File: 125653-69-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-methyl-4-(2-methylpropyl)-, acetate, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-methyl-4-(2-methylpropyl)-, acetate, (R)-(125653-69-2)
• EPA Substance Registry System: Benzenemethanol, a-methyl-4-(2-methylpropyl)-, acetate, (R)-(125653-69-2)

Safety Data

• Hazardous Substances Data: 125653-69-2(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 40150-92-3 1-(4-isobutylphenyl)ethanol 
• 138948-58-0 (RS)-p-isobutyl-1-phenylethanol acetate 

Relevant articles and documents

Highly enantioselective aminoacylase-catalyzed transesterification of secondary alcohols

The aminoacylase (N-acyl-L-amino acid amidohydrolase; E.C. 3.5.1.14) from Aspergillus melleus, a readily available inexpensive enzyme, catalyzes the transesterification of a wide range of chiral secondary arylalkanols with essentially absolute stereoselectivity (E> 500). Moreover, the productivities obtained with 1-phenylethanol, 1-phenylpropanol, 1-(1-naphthyl)ethanol and 1- (2-naphthyl)ethanol were substantially higher than those in the corresponding lipase-catalyzed transesterifications. (C) 2000 Elsevier Science Ltd.

LIPASE-CATALYZED IRREVERSIBLE TRANSESTERIFICATION USING ENOL ESTERS: XAD-8 IMMOBILIZED LIPOPROTEIN LIPASE-CATALYZED RESOLUTION OF SECONDARY ALCOHOLS

Procedures for preparation of XAD-8 immobilized lipoprotein lipase and the resolution of secondary alcohols of synthetic value in organic solvents using this immobilized enzyme have been developed.