1257228-77-5

Basic information

• Product Name: benzyl 3-acetoxy-2-vinylidenepentanoate
• Synonyms: benzyl 3-acetoxy-2-vinylidenepentanoate
• CAS NO: 1257228-77-5
• Molecular Weight: 274.317
• Mol File: 1257228-77-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl 3-acetoxy-2-vinylidenepentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 3-acetoxy-2-vinylidenepentanoate(1257228-77-5)
• EPA Substance Registry System: benzyl 3-acetoxy-2-vinylidenepentanoate(1257228-77-5)

Safety Data

• Hazardous Substances Data: 1257228-77-5(Hazardous Substances Data)

Upstream product

• 75-36-5 acetyl chloride 

Downstream Products

• 1257228-89-9 C₂₃H₂₁NO₃ 

Relevant articles and documents

Amine-catalyzed asymmetric (3 + 3) annulations of β′-acetoxy allenoates: Enantioselective synthesis of 4H-pyrans

The asymmetric (3 + 3) annulations of β′-acetoxy allenoates with either 3-oxo-nitriles or pyrazolones have been realized by using 6′-deoxy-6′-[(l)-N,N-(2,2′-oxidiethyl)-valine amido]quinine (6h) as the catalyst. The three functions of catalyst 6h, including Lewis base (quinuclidine N), H-bond donor (amide NH), and Br?nsted base (morpholine N), cooperatively take crucial roles on the chemo- and enantioselectivity, allowing for the construction of 4H-pyran and 4H-pyrano[2,3-c]pyrazole in high yields and enantioselectivity.