125761-96-8

Basic information

• Product Name: Acetic acid, [(4-nitrophenyl)sulfinyl]-, methyl ester, (R)-
• CAS NO: 125761-96-8
• Molecular Formula: C9H9NO5S
• Molecular Weight: 243.24
• Mol File: 125761-96-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Acetic acid, [(4-nitrophenyl)sulfinyl]-, methyl ester, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [(4-nitrophenyl)sulfinyl]-, methyl ester, (R)-(125761-96-8)
• EPA Substance Registry System: Acetic acid, [(4-nitrophenyl)sulfinyl]-, methyl ester, (R)-(125761-96-8)

Safety Data

• Hazardous Substances Data: 125761-96-8(Hazardous Substances Data)

Upstream product

• 100-00-5 4-chlorobenzonitrile 
• 1849-36-1 para-nitrobenzenethiol 
• 6625-35-0 methyl 2-(4-nitrophenylsulfanyl)acetate 
• 940-12-5 (R)-methyl 4-nitrophenyl sulfoxide 
• 616-38-6 carbonic acid dimethyl ester 
• 85728-59-2 (+/-)-Methyl <(4-Nitrophenyl)sulfinyl>acetate 

Relevant articles and documents

Continuous flow biocatalytic resolutions of methyl sulfinylacetates

Product inhibition was encountered for some substrates in the resolution of methyl sulfinylacetates mediated by lipase Amano AK, so an apparatus to continually extract the carboxylate product was devised. This was applied to resolve some sulfoxides with h

A FACILE ROUTE TO HOMOCHIRAL SULFOXIDES

Biocatalytic resolution of methyl sulfinylacetates afford sulfoxides (R)-(1)-(6) in very high optical yields; the products have been used in a systematic study of the "SPAC" reaction, an asymmetric synthesis of γ-hydroxy-α,β-unsaturated esters.