1258209-18-5

Basic information

• Product Name: ethyl 2-oxo-5-(5-oxo-2,5-dihydrofuran-2-yl)cyclopentanecarboxylate
• Synonyms: ethyl 2-oxo-5-(5-oxo-2,5-dihydrofuran-2-yl)cyclopentanecarboxylate
• CAS NO: 1258209-18-5
• Molecular Weight: 238.24
• Mol File: 1258209-18-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 2-oxo-5-(5-oxo-2,5-dihydrofuran-2-yl)cyclopentanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-oxo-5-(5-oxo-2,5-dihydrofuran-2-yl)cyclopentanecarboxylate(1258209-18-5)
• EPA Substance Registry System: ethyl 2-oxo-5-(5-oxo-2,5-dihydrofuran-2-yl)cyclopentanecarboxylate(1258209-18-5)

Safety Data

• Hazardous Substances Data: 1258209-18-5(Hazardous Substances Data)

Upstream product

• 61550-02-5 (furan-2-yloxy)-trimethylsilane 
• 57020-97-0 ethyl 5-oxocyclopent-1-en-1-carboxylate 

Downstream Products

• 1425314-17-5 (S)-ethyl 2-((diphenoxyphosphoryl)oxy)-5-((R)-5-oxo-2,5-dihydrofuran-2-yl)cyclopent-1-enecarboxylate 

Relevant articles and documents

Catalytic enantioselective vinylogous Mukaiyama-Michael addition of 2-silyloxyfurans to cyclic unsaturated oxo esters

The copper-catalyzed asymmetric addition of 2-silyloxyfurans to cyclic unsaturated oxo esters is reported. The reaction proceeds with excellent diastereocontrol (usually dr 99:1) and modest to high enantioselectivity, depending on the nature of the ester group and the substitution of the cyclic oxo ester. We have shown that these substrates can be transformed into a variety of building blocks bearing a γ-butenolide or γ-lactone connected to a cycloalkane or cycoalkene moiety.