125828-08-2Relevant articles and documents
The origin of β-silicon effect in electron-transfer reactions of silicon-substituted heteroatom compounds. electrochemical and theoretical studies
Yoshida, Jun-Ichi,Maekawa, Tsuyoshi,Murata, Toshiki,Matsunaga, Shin-Ichiro,Isoe, Sachihiko
, p. 1962 - 1970 (2007/10/02)
Silyl substitution at the carbon adjacent to the oxygen causes significant decrease in the electrochemical oxidation potentials of ethers and alcohols, and this effect strongly depends upon the geometry of the molecule. Two explanations are possible: (a)
