1258760-17-6

Basic information

• Product Name: C₁₆H₂₂O
• Synonyms: C₁₆H₂₂O
• CAS NO: 1258760-17-6
• Molecular Weight: 230.35
• Mol File: 1258760-17-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₂₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₂₂O(1258760-17-6)
• EPA Substance Registry System: C₁₆H₂₂O(1258760-17-6)

Safety Data

• Hazardous Substances Data: 1258760-17-6(Hazardous Substances Data)

Upstream product

• 111-25-1 1-bromo-hexane 
• 4039-82-1 Benzyl propargyl ether 

Downstream Products

• 5921-73-3 2-nonyn-1-ol 

Relevant articles and documents

Cleavage of benzyl ethers by triphenylphosphine hydrobromide

Triphenylphosphine hydrobromide was found to cleave the benzyl ethers derived from 1°, 2° alkyl, and aryl alcohols to the corresponding alcohols and benzyltriphenylphosphonium bromide in good yields. Alkene and allyl phosphonium salts were produced from the benzyl ethers with 3° alkyl and allyl groups, respectively. These results indicate that the formation of the product is determined by the relative stability of the carbocationic intermediate. The anhydrous, stoichiometric amount of PPh3·HBr offers a new and effective method for the deprotection of benzyl ethers.