1258880-41-9

Basic information

• Product Name: (E)-ethyl 3-(4-bromo-2-((E)-2-nitroprop-1-en-1-yl)phenoxy)acrylate
• Synonyms: (E)-ethyl 3-(4-bromo-2-((E)-2-nitroprop-1-en-1-yl)phenoxy)acrylate
• CAS NO: 1258880-41-9
• Molecular Weight: 356.173
• Mol File: 1258880-41-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-ethyl 3-(4-bromo-2-((E)-2-nitroprop-1-en-1-yl)phenoxy)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-ethyl 3-(4-bromo-2-((E)-2-nitroprop-1-en-1-yl)phenoxy)acrylate(1258880-41-9)
• EPA Substance Registry System: (E)-ethyl 3-(4-bromo-2-((E)-2-nitroprop-1-en-1-yl)phenoxy)acrylate(1258880-41-9)

Safety Data

• Hazardous Substances Data: 1258880-41-9(Hazardous Substances Data)

Upstream product

• 954374-78-8 ethyl (E)-3-(4-bromo-2-formylphenoxy)acrylate 
• 79-24-3 Nitroethane 

Downstream Products

• 1426657-56-8 methyl 2-(((2S,3S,4S)-6-bromo-2-((ethoxycarbonyl)methyl)-3-methyl-3-nitro-chroman-4-yl)sulfanyl)benzoate 

Relevant articles and documents

Organocatalytic asymmetric sulfa-michael/michael addition reactions: A strategy for the synthesis of highly substituted chromans with a quaternary stereocenter

Simply complex: Diverse and structurally complex chroman derivatives with a quaternary stereocenter have been obtained through the titled reaction of thiols with nitroolefin enoates using the bifunctional catalyst 1. The reaction features simple experimental procedures, high yield, enantiomeric excess, and excellent diastereoselectivity.