1259295-21-0Relevant articles and documents
Aerobic, Metal-Free, and Catalytic Dehydrogenative Coupling of Heterocycles: En Route to Hedgehog Signaling Pathway Inhibitors
Bering, Luis,Paulussen, Felix M.,Antonchick, Andrey P.
supporting information, p. 1978 - 1981 (2018/04/16)
The nitrosonium ion-catalyzed dehydrogenative coupling of heteroarenes under mild reaction conditions is reported. The developed method utilizes ambient molecular oxygen as a terminal oxidant, and only water is produced as byproduct. Dehydrogenative coupl
3,3-bis(arylbenzofurans) via a gold-catalyzed domino process
Auzias, Mathieu G.,Neuburger, Markus,Wegner, Hermann A.
experimental part, p. 2443 - 2448 (2010/11/18)
A new heterogeneous gold-catalyzed system for the domino cyclization oxidative coupling of 2-alkynyl phenols for the formation of 3,3-bisbenzofurans was developed. The substrate and the catalyst scope as well as the reaction conditions were investigated and optimized. This method provides access to this novel structural theme in two steps starting from commercially available chemicals. The molecular structure of the 3,3-bisbenzofurans was confirmed by single-crystal X-ray analysis. Georg Thieme Verlag Stuttgart · New York.