1262055-68-4

Basic information

• Product Name: N-(3,5-bis(trifluoromethyl)phenyl)-2,3-dihydro-1H-inden-1-amine
• Synonyms: N-(3,5-bis(trifluoromethyl)phenyl)-2,3-dihydro-1H-inden-1-amine
• CAS NO: 1262055-68-4
• Molecular Weight: 345.287
• Mol File: 1262055-68-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N-(3,5-bis(trifluoromethyl)phenyl)-2,3-dihydro-1H-inden-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3,5-bis(trifluoromethyl)phenyl)-2,3-dihydro-1H-inden-1-amine(1262055-68-4)
• EPA Substance Registry System: N-(3,5-bis(trifluoromethyl)phenyl)-2,3-dihydro-1H-inden-1-amine(1262055-68-4)

Safety Data

• Hazardous Substances Data: 1262055-68-4(Hazardous Substances Data)

Upstream product

• 496-11-7 INDANE 
• 328-74-5 3,5-Bis-(trifluoromethyl)aniline 

Relevant articles and documents

An Effective [FeIII(TF4DMAP)Cl] Catalyst for C-H Bond Amination with Aryl and Alkyl Azides

[FeIII(TF4DMAP)Cl] can efficiently catalyze intermolecular sp3 C-H amination using aryl azides and intramolecular sp3 C-H amination of alkyl azides in moderate-to-high product yields. At catalyst loading down to 1 mol %, the reactions display high chemo- and regioselectivity with broad substrate scope and are effective for late-stage functionalization of complex natural/bioactive molecules.

Synthesis and catalytic activity of μ-oxo ruthenium(IV) porphyrin species to promote amination reactions

This work describes the synthesis of ruthenium(IV) m-oxo porphyrin complexes of general formula [RuIV(TPP)(X)]2O which have been applied as catalysts in nitrene transfer reactions using aryl azides (ArN3) as nitrene sources. Collected data indicated that the catalytic efficiency of [RuIV(TPP)(OCH3)]2O was comparable to that of RuII(TPP)CO because of their analogous reactivity towards aryl azides to give the same catalytically active bis-imido species RuVI(TPP)(ArN)2. The reaction of [RuIV(TPP)(OCH3)]2O with Ph3CN3 or (CH3)3SiN3 afforded [RuIV(TPP)(N3)]2O which was fully characterised, its molecular structure was also determined by single crystal X-ray analysis.

Ruthenium porphyrins-catalyzed atom-efficient amination of C-H bonds by arylazides

Benzylic amines are synthesized in yield up to 90% by the Ru(TPP)CO-catalyzed amination of both exocyclic and endocyclic benzylic C-H bonds. The choice of arylazides as nitrogen sources confers to the methodology a good sustainability due to the formation of molecular nitrogen as the only stoichiometric by-product. A preliminary mechanistic investigation evidenced a critical role of the hydrocarbon concentration to drive the chemoselectivity of the reaction.