126227-56-3

Basic information

• Product Name: (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-cyano-methyl-methyl ester
• CAS NO: 126227-56-3
• Molecular Weight: 287.238
• Mol File: 126227-56-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-cyano-methyl-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-cyano-methyl-methyl ester(126227-56-3)
• EPA Substance Registry System: (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-cyano-methyl-methyl ester(126227-56-3)

Safety Data

• Hazardous Substances Data: 126227-56-3(Hazardous Substances Data)

Upstream product

• 13435-20-6 tetraethylammoniumcyanide 
• 20445-33-4 (R)-methoxytrifluoromethylphenylacetyl chloride 
• 75-07-0 acetaldehyde 

Relevant articles and documents

STEREOSELECTIVE ADDITION OF CYANIDE ION TO CHIRAL RHENIUM ?-ALDEHYDE COMPLEXES OF THE FORMULAE 5-C5H5)Re(NO)(PPh3)(η2-O=CHR)>+ BF4-; A NEW SYNTHESYS OF OPTICALLY ACTIVE CYANOHYDRIN DERIVATIVES

Reaction of optically active aldehyde complexes (+)-(RS)-5-C5H5)Re(NO)(PPh3)(η2-O=CHR)>+ BF4- and (CH3CH2)4N+ CN- gives cyanohydrin alkoxide complexes (+)-(η5-C5H5)Re(NO)(PPh3)(OCH(CN)R) (78-95percent) of 89-53percent de.The alkoxide ligands are then converted to optically active MTPA esters (96-85percent) of 90-56percent de.