1262302-54-4Relevant articles and documents
Cycloisomerization of 2-alkynylanilines to indoles catalyzed by carbon-supported gold nanoparticles and subsequent homocoupling to 3,3′-biindoles
Perea-Buceta, Jesus E.,Wirtanen, Tom,Laukkanen, Otto-Ville,Maekelae, Mikko K.,Nieger, Martin,Melchionna, Michele,Huittinen, Nina,Lopez-Sanchez, Jose A.,Helaja, Juho
, p. 11835 - 11839 (2013)
Elevated by the support: 2-Alkynyl aniline cycloisomerization to indole is catalyzed by cationic Au NPs on a carbon support. Electroneutral and rich 2-aryl indoles are further converted into 3,3′-biindoles by oxidative homocoupling that is readily catalyzed by the Au NPs on carbon, and exclusively but also somewhat sluggishly by the carbon support. Copyright
Bronsted acid catalyzed cascade reactions of 2-[(2-Aminophenyl) ethynyl]phenylamine derivatives with aldehydes: A new approach to the synthesis of 2,2′-disubstituted 1 H,1′ H -3,3′-biindoles
Arcadi, Antonio,Chiarini, Marco,D'Anniballe, Gaetano,Marinelli, Fabio,Pietropaolo, Emanuela
supporting information, p. 1736 - 1739 (2014/04/17)
An unusual Bronsted acid catalyzed cascade reaction of 2-[(2-aminophenyl)ethynyl]phenylamine derivatives with aryl(heteroaryl)aldehydes to afford an efficient alternative entry into 2,2′-disubstituted-1H, 1′H-3,3′-biindoles under metal-free conditions is reported.