1262447-22-2Relevant articles and documents
Novel and efficient synthesis of unsymmetrical trisulfides
Lach, Slawomir,Sliwka-Kaszynska, Magdalena,Witt, Dariusz
, p. 2857 - 2860 (2010)
We have developed a convenient method for the synthesis of unsymmetrical trisulfides under mild conditions in very good yields. The designed method is based on the straightforward preparation of 1-[(5,5-dimethyl-2-thioxo-1,3,2- dioxaphosphorinan-2-yl)trisulfanyl]dodecane from readily available 5,5-dimethyl-2-sulfanyl-2-thioxo-1,3,2-dioxaphosphorinane, sulfur dichloride (SCl2) and dodecane-1-thiol. The unsymmetrical trisulfides can be obtained from aliphatic, aromatic thiols and l-cysteine derivatives as well. Georg Thieme Verlag Stuttgart - New York.