1262733-10-7Relevant articles and documents
Catalytic synthesis of vinylphosphanes via calcium-mediated intermolecular hydrophosphanylation of alkynes and butadiynes
Al-Shboul, Tareq M.A.,Pálfi, Vill? K.,Yu, Lian,Kretschmer, Robert,Wimmer, Katja,Fischer, Reinald,G?rls, Helmar,Reiher, Markus,Westerhausen, Matthias
experimental part, p. 216 - 227 (2011/02/16)
The calcium complex [(thf)4Ca(PPh2)2] (1) is a very effective catalyst for the hydrophosphanylation of substituted alkynes of the type R-CC-R (R = Me, Ph) yielding (E)-1,2-diphenyl-1- diphenylphosphanylethene (2a) and (Z)-