126314-19-0Relevant articles and documents
Titanocene(III) chloride mediated reductive cleavage of arylcyclopropyl ketones
Paira,Mandal,Roy
experimental part, p. 573 - 577 (2010/12/25)
Titanocene(III) chloride (Cp2TiCl) mediated cleavage of arylcyclopropyl ketones has been accomplished. Both saturated and β-H eliminated unsaturated aromatic compounds are formed in different ratio depending on the substrate. Ti(III) species has been prepared in situ from commercially available titanocene dichloride (Cp2TiCl2) and zinc dust in THF.