1263293-65-7Relevant articles and documents
Botrylactone: New interest in an old molecule - Review of its absolute configuration and related compounds
Moraga, Javier,Pinedo, Cristina,Durán-Patrón, Rosa,Collado, Isidro G.,Hernández-Galán, Rosario
experimental part, p. 417 - 420 (2011/03/19)
The absolute configuration of botrylactone, a unique compound with an interesting polyketide lactone skeleton with two oxirane bridges previously isolated from Botrytis cinerea and described as a powerful antibiotic, has been reviewed on the basis of sign of the optical rotation, NOE experiments and NMR method. The isolation of 7-deoxybotrylactone and 5-hydroxy-7-(4-hydroxydec-2(3)- enoyl) botrylactone enables us to characterize an intriguing new family of compounds with this interesting polyketide skeleton. A common biosynthetic origin with botcinin derivatives is proposed. Copyright