126396-30-3

Basic information

• Product Name: cis-(+/-)-2-(4-bromophenyl)-3,6-dimethyl-3,6-dihydro-2H-1,2-thiazine
• CAS NO: 126396-30-3
• Molecular Weight: 284.22
• Mol File: 126396-30-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: cis-(+/-)-2-(4-bromophenyl)-3,6-dimethyl-3,6-dihydro-2H-1,2-thiazine(CAS DataBase Reference)
• NIST Chemistry Reference: cis-(+/-)-2-(4-bromophenyl)-3,6-dimethyl-3,6-dihydro-2H-1,2-thiazine(126396-30-3)
• EPA Substance Registry System: cis-(+/-)-2-(4-bromophenyl)-3,6-dimethyl-3,6-dihydro-2H-1,2-thiazine(126396-30-3)

Safety Data

• Hazardous Substances Data: 126396-30-3(Hazardous Substances Data)

Upstream product

• 5194-50-3 (E,Z)-2,4-hexadiene 
• 157736-04-4 C₉H₁₃BrClNSSi 
• 182260-22-6 C₆H₅BrClNS 
• 106-40-1 4-bromo-aniline 
• 5194-51-4 (2E,4E)-hexa-2,4-diene 
• 118622-96-1 N-(4-bromophenylaminothio)phthalimide 
• 63911-87-5 N-(trimethylsilyl)-4-bromoaniline 

Relevant articles and documents

Metal-assisted fragmentation of N-aryl- and -alkyl-N-trimethylsilylaminosulfur chlorides and N-aryl- and -alkyl-aminosulfur chlorides in the presence of conjugated dienes: Synthesis and reactivity of 2-substituted-3,6-dihydro-1,2-thiazines

N-Alkyl- and -aryl-N-trimethylsilylaminosulfur chlorides 2 and N-aryl- and -alkyl-aminosulfur chlorides 8 fragment in the presence of silver ions and a conjugated diene to yield 2-substituted-3,6-dihydro-1,2-thiarines 6 as the major products, possibly via

THE STEREOCHEMICAL OUTCOME OF DIENE ADDITIONS TO THIONITROSOARENES (ArN=S)

Thionitrosoarenes (ArN=S) react efficiently with (E,E)- and (E,Z)-hexadienes to yield 1,2-thiazine adducts in which the stereochemistry of the diene is retained.