126435-89-0

Basic information

• Product Name: 2-Penten-1-ol, 5-phenyl-, acetate, (2E)-
• CAS NO: 126435-89-0
• Molecular Formula: C13H16O2
• Molecular Weight: 204.269
• Mol File: 126435-89-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Penten-1-ol, 5-phenyl-, acetate, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Penten-1-ol, 5-phenyl-, acetate, (2E)-(126435-89-0)
• EPA Substance Registry System: 2-Penten-1-ol, 5-phenyl-, acetate, (2E)-(126435-89-0)

Safety Data

• Hazardous Substances Data: 126435-89-0(Hazardous Substances Data)

Upstream product

• 64-19-7 acetic acid 
• 75553-23-0 (E)-5-phenyl-2-penten-1-ol 
• 108-24-7 acetic anhydride 
• 104-53-0 3-phenyl-propionaldehyde 
• 55282-95-6 ethyl (2E)-5-phenylpent-2-enoate 
• 590-97-6 acetoxymethyl bromide 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 75553-23-0 (E)-5-phenyl-2-penten-1-ol 
• 1745-16-0 5-phenylpent-2-ene 
• 1075-74-7 5-phenylpent-1-ene 
• 639005-99-5 (E)-(5-chloropent-3-en-1-yl)benzene 
• 945428-61-5 (E)-1-benzyloxy-5-phenylpent-2-ene 
• 147330-82-3 (E)-5-phenyl-1-triethylgermyl-2-pentane 
• 1000376-25-9 (S)-4,4,5,5-tetramethyl-2-[5-phenyl-1-penten-3-yl]-1,3,2-dioxaborolane 
• 1000376-26-0 (3R)-3-(4',4',5',5'-tetramethyl-1',3',2’-dioxaborolanyl)-5-phenylpent-1-ene 
• 1607805-12-8 C₁₃H₁₄F₂ 
• 1607805-00-4 (3-allyl-4,4-difluorohex-5-en-1-yl)benzene 
• 1607805-34-4 C₁₂H₁₄F₂O 

Relevant articles and documents

Enantioselective C-C Bond Formation during the Oxidation of 5-Phenylpent-2-enyl Carboxylates with Hypervalent Iodine(III)

The oxidation of (5-acyloxypent-3-enyl)benzene with hypervalent iodine(III) afforded 2-oxy-1-(oxymethyl)tetrahydronaphthalene under metal-free conditions. The acyloxy group may nucleophilically participate in the oxidative cyclization. A lactate-based chi

Iridium-catalysed allylic substitution: Stereochemical aspects and isolation of IrIII complexes related to the catalytic cycle

Ir-catalysed allylic alkylations of enantiomerically enriched monosubstituted allylic acetates proceed with up to 87% retention of configuration using P(OPh)3 as ligand. High retention enantioselectivity of up to 86% ee in asymmetric allylic alkylations of achiral or racemic substrates is achieved with monodentate phosphorus amidites as ligands. Lithium N-tosylbenzylamide was identified as a suitable nucleophile for allylic aminations. Of particular importance is the use of lithium chloride as an additive, generally leading to increased enantioselectivities. Two (π-allyl)IrIII complexes were characterised by X-ray crystal structure analysis and spectroscopic data.

Stereoselectivity and regioselectivity in the segment-coupling prins cyclization

The scope of the segment-coupling Prins cyclization has been investigated. The method is outlined in Scheme 1 and involves esterification of a homoallylic alcohol.(1), reductive acetylation to give the α-acetoxy ether (3), and cyclization on treatment wit