126566-51-6Relevant articles and documents
Synthesis and characterization of allylic dihaloboranes
Le Serre, Stéphanie,Guillemin, Jean-Claude
, p. 5844 - 5848 (2008/10/08)
Volatile allylic dihaloboranes have been prepared and characterized by 1H, 11B, 13C, and 19F NMR spectroscopy and mass spectrometry. The stability (τ1/2) of such compounds in dilute CDCl3 solutions depends on the substituents and the halides and ranges from a few minutes (allylic dibromoboranes) to several days (allylic difluoroboranes). Allyldihaloborane etherates were obtained by addition of diethyl ether to the corresponding free allyldihaloborane.