1265897-73-1

Basic information

• Product Name: methyl 1-(4-methoxyphenyl)-1,4,5,6-tetrahydrocyclopenta[c]pyrazole-3-carboxylate
• CAS NO: 1265897-73-1
• Molecular Weight: 272.304
• Mol File: 1265897-73-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 1-(4-methoxyphenyl)-1,4,5,6-tetrahydrocyclopenta[c]pyrazole-3-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 1-(4-methoxyphenyl)-1,4,5,6-tetrahydrocyclopenta[c]pyrazole-3-carboxylate(1265897-73-1)
• EPA Substance Registry System: methyl 1-(4-methoxyphenyl)-1,4,5,6-tetrahydrocyclopenta[c]pyrazole-3-carboxylate(1265897-73-1)

Safety Data

• Hazardous Substances Data: 1265897-73-1(Hazardous Substances Data)

Upstream product

• 1192-04-7 1-bromocyclopentene 
• 1265897-67-3 3,3a,4,5,6,7,7a-hepta(methoxycarbonyl)-1-(4-methoxyphenyl)-3a,7a-dihydroindazole 
• 142-29-0 cyclopentene 

Relevant articles and documents

Generation of 1-aryl-3-methoxycarbonylnitrilimines and their reaction with halogen-containing unsaturated compounds

Thermal decomposition of 1-(4-methoxyphenyl)- and 1-(4-fluorophenyl) hepta(methoxycarbonyl)-3a,7a-dihydroindazoles at 135 C in the presence of allyl or propargyl halides leads to the elimination of hexamethyl benzenehexacarboxylate and the formation of the corresponding pyrazolines or pyrazoles as the products of 1,3-dipolar cycloaddition of 1-aryl-3- methoxycarbonylnitrilimines to the multiple bonds of the substrates used. In the case of vinyl halides, the products of the target reactions are either obtained in low yields or nonexistent, with a side conversions taking place instead. Thus, for example, in the case of 1,1-dichloro-4-methylpenta-1,3-diene, besides hexamethyl benzenehexacarboxylate, 3,5,5-trichloro-2-methylpent-4-en-2-ol and arylchlorohydrazones MeO2CC(Cl)=N-NHAr were unexpectedly isolated as the main products, as well.