126615-42-7

Basic information

• Product Name: 6(R)-<1(R)-Methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>-4(R)-<1(S)-methyl-2-oxoethyl>-2(R),5(R)-dimethyl-2-(p-methoxyphenyl)-1,3-dioxane
• CAS NO: 126615-42-7
• Molecular Weight: 574.833
• Mol File: 126615-42-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6(R)-<1(R)-Methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>-4(R)-<1(S)-methyl-2-oxoethyl>-2(R),5(R)-dimethyl-2-(p-methoxyphenyl)-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: 6(R)-<1(R)-Methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>-4(R)-<1(S)-methyl-2-oxoethyl>-2(R),5(R)-dimethyl-2-(p-methoxyphenyl)-1,3-dioxane(126615-42-7)
• EPA Substance Registry System: 6(R)-<1(R)-Methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>-4(R)-<1(S)-methyl-2-oxoethyl>-2(R),5(R)-dimethyl-2-(p-methoxyphenyl)-1,3-dioxane(126615-42-7)

Safety Data

• Hazardous Substances Data: 126615-42-7(Hazardous Substances Data)

Upstream product

• 126720-97-6 3(S)-<1(R),4-Dimethyl-2(E)-pentenyl>-4(S)-methyl-5(S)-<1(R)-methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>dihydro-2(3H)-furanone 
• 126615-40-5 6(S)-<1(R),4-Dimethyl-2(E)-pentenyl>-4(S)-<1(R)-methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>-2(S),5(S)-dimethyl-2-(p-methoxyphenyl)-1,3-dioxane 
• 115047-24-0 (4S,5S)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3-((E)-(R)-1,4-dimethyl-pent-2-enyl)-4-methyl-2-oxo-tetrahydro-furan-3-carboxylic acid methyl ester 
• 110410-93-0 (4S,5S)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-4-methyl-2-oxo-tetrahydro-furan-3-carboxylic acid methyl ester 
• 126720-99-8 1-<(tert-Butyldiphenylsilyl)oxy>-2(R),4(S),6(R),9-tetramethyl-7(E)-decene-3(R),5(S)-diol 
• 412342-76-8 (4S,5S)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-4-methyl-dihydro-furan-2-one 
• 126615-38-1 (E)-(2S,3R)-3,6-Dimethyl-2-[(S)-1-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-hept-4-enoic acid 
• 126615-39-2 3(S)-<1(R),4-Dimethyl-2(E)-pentenyl>-4(S)-methyl-5(S)-<1(R)-methyl-2-hydroxyethyl>dihydro-2(3H)-furanone 
• 126720-95-4 4(S)-<1(S)-Methyl-2-cyanoethyl>-2,2,5(R)-trimethyl-1,3-dioxane 
• 126721-03-7 (4α,5β)-4,5-dihydro-5-(2-hydroxy-1-methylethyl)-4-methyl-2(3H)-furanone 
• 51440-56-3 1-Methoxy-4-(1-methoxy-vinyl)-benzene 
• 126615-41-6 (R)-2-[(2S,4S,5S,6R)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2-(4-methoxy-phenyl)-2,5-dimethyl-[1,3]dioxan-4-yl]-propan-1-ol 

Downstream Products

• 126615-44-9 4(S)-<1(R)-Methyl-2-hydroxybutyl>-6(R)-<1(R)-methyl-2-hydroxyethyl>-2(R),5(R)-dimethyl-2-(p-methoxyphenyl)-1,3-dioxane 
• 126615-45-0 4(R)-<1(S)-Methyl-2-oxobutyl>-6(S)-<1(S)-methyl-2-oxoethyl>-2(R),5(R)-dimethyl-2-(p-methoxyphenyl)-1,3-dioxane 
• 87697-98-1 Denticulatin A 
• 126615-48-3 6(R)-<1(S)-Methyl-2-oxobutyl>-4(S)-<1(S),3(RS),5(R),7-tetramethyl-2,4-dioxo-7(E)-decenyl>-2(S),5(S)-dimethyl-2-(p-methoxyphenyl)-1,3-dioxane 

Relevant articles and documents

Total Synthesis of (-)-Denticulatins A and B: Marine Polypropionates from Siphonaria denticulata

A synthesis of the marine polypropionates (-)-denticulatin A (2a) and B (2b) is described.The targets, which are β-hydroxy ketones wherein the hydroxyl group is also a tertiary hemiketal, are sensitive to acid dehydration.An open chain form (26) of the de