1266356-15-3

Basic information

• Product Name: 3-(6-tert-butyldimethylsilyloxy-1-hexen)-yl benzoate
• Synonyms: 3-(6-tert-butyldimethylsilyloxy-1-hexen)-yl benzoate
• CAS NO: 1266356-15-3
• Molecular Weight: 334.531
• Mol File: 1266356-15-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-(6-tert-butyldimethylsilyloxy-1-hexen)-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(6-tert-butyldimethylsilyloxy-1-hexen)-yl benzoate(1266356-15-3)
• EPA Substance Registry System: 3-(6-tert-butyldimethylsilyloxy-1-hexen)-yl benzoate(1266356-15-3)

Safety Data

• Hazardous Substances Data: 1266356-15-3(Hazardous Substances Data)

Upstream product

• 85807-84-7 tert-butyl(5-hexenyloxy)dimethylsilane 
• 94-36-0 dibenzoyl peroxide 
• 73448-13-2 tert-butyldimethylsilyl hex-5-yn-1-yl ether 
• 65-85-0 benzoic acid 

Relevant articles and documents

Copper-catalyzed regioselective allylic oxidation of olefins via C–H activation

A regioselective oxidation of allylic C–H bond to C–O bond catalyzed by copper (I) was developed with diacyl peroxides as oxidants. The oxidation of allylic C–H bond was accomplished with good yield and regioselectivity under mild reaction conditions. This method has a broad substrate scope including cyclic olefins, terminal and internal acyclic olefins and allyl benzene compounds. The reaction proceeds by a radical mechanism as suggested by spin trapping experiments.