126646-43-3Relevant articles and documents
Intriguing C-H?Cu interactions in bis-(phenanthroline)Cu(i) redox mediators for dye-sensitized solar cells
Colombo, Alessia,Ossola, Rachele,Magni, Mirko,Roberto, Dominique,Jacquemin, Denis,Castellano, Carlo,Demartin, Francesco,Dragonetti, Claudia
supporting information, p. 1018 - 1022 (2018/02/07)
We have synthesized and characterized a series of bis-(phenanthroline)Cu(i) complexes of interest as redox mediators for dye-sensitized solar cells. This study led to the discovery of intriguing anagostic interactions between the hydrogen atom and the copper center as evidenced by X-ray diffraction studies on a single crystal. Remarkably, an anagostic interaction was found between a H atom of a methyl group and a copper site.