126651-12-5

Basic information

• Product Name: biphenyl-4-carboxaldehyde dimethyl acetal
• Synonyms: biphenyl-4-carboxaldehyde dimethyl acetal
• CAS NO: 126651-12-5
• Molecular Weight: 228.291
• Mol File: 126651-12-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: biphenyl-4-carboxaldehyde dimethyl acetal(CAS DataBase Reference)
• NIST Chemistry Reference: biphenyl-4-carboxaldehyde dimethyl acetal(126651-12-5)
• EPA Substance Registry System: biphenyl-4-carboxaldehyde dimethyl acetal(126651-12-5)

Safety Data

• Hazardous Substances Data: 126651-12-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 644-08-6 4-Methylbiphenyl 

Downstream Products

• 868662-48-0 4-[3-(4-biphenyl)-5-hydroxy-5-trifluoromethyl-4,5-dihydro-1H-pyrazol-1-yl]-7-chloroquinoline 
• 186023-45-0 (2S,4S)-3-((S)-2-Benzyloxycarbonylamino-propionyl)-2-biphenyl-4-yl-oxazolidine-4-carboxylic acid 
• 3218-36-8 4-Phenylbenzaldehyde 

Relevant articles and documents

SYNTHESIS OF PHENYL SUBSTITUTED CYCLOHEXA-1,4-DIENES AND CYCLOHEXA-2,5-DIENONES BY ANODIC METHOXYLATION OF ALKYLBIPHENYLS

The anodic methoxylation of a series of alkylbiphenyls (2-, 3-, 4-methylbiphenyl, 3,3'-, 4,4'-dimethylbiphenyl, 4-ethylbiphenyl and 4,4'-di-tert-butylbiphenyl) carried out under constant current intensity afforded, in a process of two electrons, a number of cis/trans cyclohexa-1,4-dienes and, in a process of four electrons, a number of cyclohexa-2,5-dienones after acidic hydrolysis of the corresponding cyclohexa-1,4-diene ketals.In some cases, side-chain substitution products were also obtained.Probable mechanisms are proposed.