1266679-65-5Relevant articles and documents
A highly para-selective copper(II)-catalyzed direct arylation of aniline and phenol derivatives
Ciana, Claire-Lise,Phipps, Robert J.,Brandt, Jochen R.,Meyer, Falco-Magnus,Gaunt, Matthew J.
supporting information; experimental part, p. 458 - 462 (2011/03/16)
In short order: A copper-catalyzed Friedel-Crafts-type strategy has been developed for the title reaction. An iterative C-H arylation strategy has also been demonstrated for the functionalization of anilines by sequentially delivering different aromatic groups to the para, ortho, and meta positions (see scheme, Bn=benzyl, Piv=pivaloyl).
