126708-68-7

Basic information

• Product Name: ((Z)-5-Methyl-hex-2-enyl)-benzene
• Synonyms: ((Z)-5-Methyl-hex-2-enyl)-benzene
• CAS NO: 126708-68-7
• Molecular Weight: 174.286
• Mol File: 126708-68-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((Z)-5-Methyl-hex-2-enyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((Z)-5-Methyl-hex-2-enyl)-benzene(126708-68-7)
• EPA Substance Registry System: ((Z)-5-Methyl-hex-2-enyl)-benzene(126708-68-7)

Safety Data

• Hazardous Substances Data: 126708-68-7(Hazardous Substances Data)

Upstream product

• 676-58-4 methylmagnesium chloride 
• 300-57-2 allylbenzene 
• 691-37-2 4-Methyl-1-pentene 

Relevant articles and documents

Use of the 2-Pyridinesulfonyloxy Leaving Group for the Fast Copper-Catalyzed Coupling Reaction at Secondary Alkyl Carbons with Grignard Reagents

Investigation of the copper-catalyzed coupling reaction of 2-pyridinesulfonates with Grignard reagents revealed that reactions with catalytic Cu(OTf)2 were completed in 40 min. The results differed from those of the previous CuI-catalyzed reactions of tosylates in the presence of additives (LiOMe and TMEDA) for 12-24 h. It was shown that the preferred coordination of the leaving group to the reagents accelerated the reaction. Successful reagents were MeMgCl and other RMgX. Complete inversion was established.