126787-34-6

Basic information

• Product Name: Carbamic acid, [(1R)-1-methyl-2-oxo-2-(phenylamino)ethyl]-, 9H-fluoren-9-ylmethyl ester
• CAS NO: 126787-34-6
• Molecular Formula: C24H22N2O3
• Molecular Weight: 386.45
• Mol File: 126787-34-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [(1R)-1-methyl-2-oxo-2-(phenylamino)ethyl]-, 9H-fluoren-9-ylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(1R)-1-methyl-2-oxo-2-(phenylamino)ethyl]-, 9H-fluoren-9-ylmethyl ester(126787-34-6)
• EPA Substance Registry System: Carbamic acid, [(1R)-1-methyl-2-oxo-2-(phenylamino)ethyl]-, 9H-fluoren-9-ylmethyl ester(126787-34-6)

Safety Data

• Hazardous Substances Data: 126787-34-6(Hazardous Substances Data)

Upstream product

• 35661-38-2 N-(9-fluorenylmethoxycarbonyl)-D-alanine 
• 62-53-3 aniline 
• 98-80-6 phenylboronic acid 

Relevant articles and documents

Copper catalyzed aryl amidation between Nα-Fmoc-protected amino-acid azides and aryl boronic acids

A simple and efficient method for the synthesis of aryl amides via oxidative copper-catalyzed coupling of commercially available aryl boronic acids and bench stable Nα-protected amino-acid azides is reported. The potential utility of this protocol is demonstrated through a survey of diversely substituted aryl boronic acids and several side-chain functionalized amino-acid azides, leading to the preparation of the desired amidated products in good to excellent yields. This amide synthesis is suitable for the preparation of amides (such as peptide aryl amides and sterically hindered amino acids) that are not or hardly accessible via classical approaches.