126800-02-0Relevant articles and documents
Porphyrin-based mixed-valent Ag(i)/Ag(ii) and Cu(i)/Cu(ii) networks as efficient heterogeneous catalysts for the azide-alkyne "click" reaction and promising oxidation of ethylbenzene
Jiang, Wei,Yang, Jin,Liu, Ying-Ying,Ma, Jian-Fang
, p. 1373 - 1376 (2016)
By using a new porphyrin-based linker, two unusual mixed-valent Ag(i,ii)- and Cu(i,ii)-organic networks were synthesized. Most strikingly, 1 and 2 exhibit highly efficient catalytic activities for the azide-alkyne "click" reaction and oxidation of ethylbe
Construction of Stable Metal–Organic Framework Platforms Embedding N-Heterocyclic Carbene Metal Complexes for Selective Catalysis
Kim, Hyunyong,Kim, Hyunseok,Kim, Kimoon,Lee, Eunsung
supporting information, p. 18687 - 18697 (2021/12/17)
We report a bottom-up approach to immobilize catalysts into MOFs, including copper halides and gold chloride in a predictable manner. Interestingly, the structures of MOFs bearing NHC metal complexes maintained a similar 4-fold interpenetrated cube. They
Resorcin[4]arene-based Cu(I) binuclear and mononuclear complexes as efficient catalysts for azide-alkyne cycloaddition reactions
Qin, Qian,Xu, Guo-Hai,Liu, Ying-Ying,Ma, Jian-Fang
, (2021/01/12)
In this study, three fascinating resorcin[4]arene-based Cu(I) complexes, named [CuCl (TPC4R)] (1), [CuBr (TPC4R)] (2), and [Cu2I2(TPC4R)] (3) were prepared by using a pyrimidine-functionalized resorcin[4]arene ligand (TPC4R). In 1 an
Dipolar HCP materials as alternatives to DMF solvent for azide-based synthesis
Bai, Rongxian,Gao, Feng,Gu, Yanlong,Li, Minghao
, p. 7499 - 7505 (2021/10/12)
Hypercrosslinked polymers HCP-DMF and HCP-DMF-SO3H containing abundant and flexible DMF moieties were designed and synthesized. Benefitting from the solvation microenvironment provided by the pseudo-DMF moities, the polar HCPs manifested outstanding performances in the conversions of NaN3 to benzylic azides and 1,2,3-triazoles in EtOH (95%), respectively, avoiding the use of risky DMF and improving the separation processes of the products.