1268368-57-5

Basic information

• Product Name: (R,E)-9-phenylnon-5-ene-1,7-diol
• Synonyms: (R,E)-9-phenylnon-5-ene-1,7-diol
• CAS NO: 1268368-57-5
• Molecular Weight: 234.338
• Mol File: 1268368-57-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R,E)-9-phenylnon-5-ene-1,7-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (R,E)-9-phenylnon-5-ene-1,7-diol(1268368-57-5)
• EPA Substance Registry System: (R,E)-9-phenylnon-5-ene-1,7-diol(1268368-57-5)

Safety Data

• Hazardous Substances Data: 1268368-57-5(Hazardous Substances Data)

Upstream product

• 170646-96-5 N-methoxy-N-methyl-3-phenylpropionamide 
• 73448-13-2 tert-butyldimethylsilyl hex-5-yn-1-yl ether 
• 1268368-81-5 (R)-9-(tert-butyldimethylsilyloxy)-1-phenylnon-4-yn-3-ol 
• 1268368-80-4 9-(tert-butyldimethylsilyloxy)-1-phenylnon-4-yn-3-one 

Downstream Products

• 1268368-69-9 (S,E)-2-(4-phenylbut-1-en-1-yl)tetrahydro-2H-pyran 

Relevant articles and documents

Chirality transfer in Au-catalyzed cyclization reactions of monoallylic diols: Selective access to specific enantiomers based on olefin geometry

The gold(I)-catalyzed cyclization of monoallylic diols to form tetrahydropyrans is shown to be highly stereoselective when chiral allylic alcohols are employed. Substrates that differ only in olefin geometry provide enantiomeric products from formal SN2′ reactions in high yields with excellent chirality transfer. The allylic alcohol stereochemistry also efficiently controls the facial selectivity when the substrates include additional stereocenters.