1268526-52-8

Basic information

• Product Name: C₃₁H₄₃Cl₂CuN₂O
• Synonyms: C₃₁H₄₃Cl₂CuN₂O
• CAS NO: 1268526-52-8
• Molecular Weight: 594.147
• Mol File: 1268526-52-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₁H₄₃Cl₂CuN₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₁H₄₃Cl₂CuN₂O(1268526-52-8)
• EPA Substance Registry System: C₃₁H₄₃Cl₂CuN₂O(1268526-52-8)

Safety Data

• Hazardous Substances Data: 1268526-52-8(Hazardous Substances Data)

Upstream product

• 1268526-51-7 [CuCl(^ClIPr)] 
• 865-48-5 sodium t-butanolate 

Downstream Products

• 1446705-85-6 C₃₃H₄₆BCl₂CuN₂O₂ 

Relevant articles and documents

Highly selective copper-catalyzed hydroboration of allenes and 1,3-dienes

The highly selective copper-catalyzed hydroboration of allenes has been developed. Allylboranes and alkenylboranes were selectively prepared by the judicious choice of catalytic species (copper hydride and boryl copper). Furthermore, two types of alkenylboranes could be selectively synthesized by the choice of an appropriate ligand. Mechanistic studies confirmed that the protonation of a (Z)-σ-allyl copper species, which was isolated and structurally characterized by single-crystal X-ray diffraction, was a key step in these reactions. Besides allenes, this method is also applicable to the selective hydroboration of 1,3-diene derivatives to afford allylboranes and homoallylboranes. Copyright