126971-21-9Relevant articles and documents
Face-Selective and endo-Selective Cycloadditions with Enantiomerically Pure Cyclopentadienes
Beckmann, Marion,Meyer, Thorsten,Schulz, Frauke,Winterfeldt, Ekkehard
, p. 2505 - 2510 (2007/10/02)
A general synthetic route to the enantiopure bicyclic cyclopentadienes (S)-3 and (R)-3 of the hydrindane series, starting from the Hajos-Wiechert ketone 4 or its enantiomer is described.Reasons for the excellent face and endo selectivity of cycloadditions
Chiral Cyclopentadienes
Matcheva, Katerina,Beckmann, Marion,Schomburg, Dietmar,Winterfeldt, Ekkehard
, p. 814 - 817 (2007/10/02)
Efficient syntheses of enantiomerically pure cyclopentadienes which undergo stereoselective and regioselective high pressure cycloadditions with nonsymmetric dienophiles are reported.As these compounds show a quite high chemical as well as thermal stabili