127065-59-2

Basic information

• Product Name: Mo(C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅))(CO)3
• CAS NO: 127065-59-2
• Molecular Weight: 579.55
• Mol File: 127065-59-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mo(C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅))(CO)3(CAS DataBase Reference)
• NIST Chemistry Reference: Mo(C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅))(CO)3(127065-59-2)
• EPA Substance Registry System: Mo(C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅))(CO)3(127065-59-2)

Safety Data

• Hazardous Substances Data: 127065-59-2(Hazardous Substances Data)

Upstream product

• 127065-64-9 Mo(C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅))(CO)3⁽¹⁺⁾*PF₆^(1-)={Mo(C₂H₄N(CH₂C₆H₅))3(CO)3}(PF₆) 
• 125262-43-3 N,N',N''-tribenzyl-1,4,7-triazacyclononane 
• 13939-06-5 molybdenum hexacarbonyl 

Downstream Products

• 127065-72-9 Mo(C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅))(CO)3(Br)⁽¹⁺⁾*PF₆^(1-)={Mo(C₂H₄N(CH₂C₆H₅))3(CO)3(Br)}(PF₆) 
• 127065-64-9 Mo(C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅))(CO)3⁽¹⁺⁾*PF₆^(1-)={Mo(C₂H₄N(CH₂C₆H₅))3(CO)3}(PF₆) 
• 127065-75-2 Mo(C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅)C₂H₄N(CH₂C₆H₅))(CO)3⁽¹⁺⁾*PF₆^(1-)*CH(O)N(CH₃)2={Mo(C₂₇H₃₃N₃)(CO)3}(PF₆)*CH(O)N(CH₃)2 

Relevant articles and documents

Stable cationic 17-electron [LM(CO)3]+ species (L = 1,4,7-tribenzyl-1,4,7-triazacyclononane; M = Cr, Mo, W): Synthesis, spectroscopic properties, and reactivity. Crystal structure of [LMo(CO)3](PF6)·dmf

The neutral 18-electron complexes LM(CO)3, where L, represents the tridentate capping ligand 1,4,7-tribenzyl-1,4,7-triazacyclononane and M is Cr, Mo, or W, were prepared from M(CO)6 and L in dimethylformamide (dmf) at 150°C. Oxidation of these diamagnetic complexes in CH2Cl2 with ferrocenium hexafluorophosphate affords the cationic 17-electron species [LM-(CO)3]PF6 in good yields. Magnetic susceptibility measurements and ESR spectroscopy confirm the presence of one unpaired electron per cation in these materials. The crystal structure of [LMo(CO)3](PF6)·dmf has been determined by X-ray crystallography (trigonal, space group R3; a = 18.299 (4), c = 24.852 (7) A?; Z = 9). The molybdenum atom is in a pseudooctahedral environment comprising three facially coordinated amine nitrogen atoms and three carbonyl ligands. The cation possesses crystallographically imposed C3 symmetry. Cyclic voltammetry reveals a reversible one-electron oxidation of LM(CO)3 species in dmf at -0.52 V vs Fc+/Fc for the chromium complex, at -0.23 V vs Fc+/Fc for the molybdenum complex, and at -0.305 V vs Fc+/Fc for the tungsten complex. At more anodic potentials a second irreversible oxidation wave has been observed. The reactivity of the LM(CO)3 species has been briefly investigated.