127086-32-2

Basic information

• Product Name: (+/-)-(2β,3α,3aα)-2-<4-<(tert-butyldimethylsilyl)oxy>-3-methoxyphenyl>-3,3a-dihydro-5-methoxy-3-methyl-3a-(2-propenyl)-6(2H)-benzofuranone
• CAS NO: 127086-32-2
• Molecular Weight: 456.654
• Mol File: 127086-32-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+/-)-(2β,3α,3aα)-2-<4-<(tert-butyldimethylsilyl)oxy>-3-methoxyphenyl>-3,3a-dihydro-5-methoxy-3-methyl-3a-(2-propenyl)-6(2H)-benzofuranone(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(2β,3α,3aα)-2-<4-<(tert-butyldimethylsilyl)oxy>-3-methoxyphenyl>-3,3a-dihydro-5-methoxy-3-methyl-3a-(2-propenyl)-6(2H)-benzofuranone(127086-32-2)
• EPA Substance Registry System: (+/-)-(2β,3α,3aα)-2-<4-<(tert-butyldimethylsilyl)oxy>-3-methoxyphenyl>-3,3a-dihydro-5-methoxy-3-methyl-3a-(2-propenyl)-6(2H)-benzofuranone(127086-32-2)

Safety Data

• Hazardous Substances Data: 127086-32-2(Hazardous Substances Data)

Upstream product

• 127086-31-1 (Z)-1-<(tert-butyldimethylsilyl)oxy>-2-methoxy-4-(1-propenyl)benzene 
• 78095-18-8 2-<3-<(methylsulfonyl)oxy>propyl>-4,4,5-trimethoxycyclohexa-2,5-dienone 

Downstream Products

• 127102-42-5 (+/-)-(2α,4α,5β,5aα)-4-<4-<(tert-butyldimethylsilyl)oxy>-3-methoxyphenyl>-2,5a-mathano-7-methoxy-5-methyl-8H-2,3,4,5-tetrahydro-1-benzoxepin-8-one 
• 65527-31-3 (+/-)-(6-endo,7-exo)-7-(4-hydroxy-3-methoxyphenyl)-3-methoxy-6-methyl-5-(2-propenyl)bicyclo<3.2.1>oct-3-ene-2,8-dione 
• 65527-31-3 (+/-)-(6-exo,7-endo)-7-(4-hydroxy-3-methoxyphenyl)-3-methoxy-6-methyl-5-(2-propenyl)bicyclo<3.2.1>oct-3-ene-2,8-dione 

Relevant articles and documents

Synthesis of Neolignans via a Proposed Biosynthetic Intermediate. Total Synthesis of (+/-)-Futoenone

The attempted spectroscopic observation of a quinone methide proposed to be an intermediate in the biosynthesis of neolignans is reported.The results afforded substantial indirect evidence for the formation of quinone methide 3.The synthesis of racemic bi