1272565-10-2

Basic information

• Product Name: C₂₂H₁₈O₄
• Synonyms: C₂₂H₁₈O₄
• CAS NO: 1272565-10-2
• Molecular Weight: 346.383
• Mol File: 1272565-10-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₂H₁₈O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₁₈O₄(1272565-10-2)
• EPA Substance Registry System: C₂₂H₁₈O₄(1272565-10-2)

Safety Data

• Hazardous Substances Data: 1272565-10-2(Hazardous Substances Data)

Upstream product

• 615-06-5 3-furan-2-yl-3-oxo-propionic acid methyl ester 
• 947-91-1 Diphenylacetaldehyde 
• 1192-62-7 1-(2-furyl)-1-ethanone 

Downstream Products

• 1272565-40-8 C₂₀H₁₆O₂ 

Relevant articles and documents

Divergent reaction pathways of a cationic intermediate: Rearrangement and cyclization of 2-substituted furyl and benzofuryl enones catalyzed by iridium(III)

In contrast to 2-substituted pyrrole enones, furyl and benzofuryl enones do not undergo the Nazarov electrocyclization. Instead, these furyl and benzofuryl enones exhibit unusual rearrangement sequences in the presence of catalytic amounts of [IrBr(CO)(DIM)((R)-(+)-BINAP)](SbF6)2 (1; DIM = diethylisopropylidene malonate) and AgSbF6 (1:1). A 1,2-H shift followed by intramolecular Friedel-Crafts alkylation leads to synthetically valuable cyclohexanones with furanylic quaternary centers. The electrophilicity of 1 is essential for this rearrangement.