127275-19-8

Basic information

• Product Name: 1-amino>-3-butene
• Synonyms: 1-amino>-3-butene
• CAS NO: 127275-19-8
• Molecular Weight: 247.456
• Mol File: 127275-19-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-amino>-3-butene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-amino>-3-butene(127275-19-8)
• EPA Substance Registry System: 1-amino>-3-butene(127275-19-8)

Safety Data

• Hazardous Substances Data: 127275-19-8(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 5162-44-7 1-bromo-4-butene 
• 53215-95-5 N-(trimethylsilylmethyl)benzylamine 

Downstream Products

• 96240-08-3 N-benzyl-3-methylpyrrolidine 

Relevant articles and documents

Photoinduced electron transfer (PET) promoted cyclisations of 1-[N-alkyl-N-(trimethylsilyl)methyl]amines tethered to proximate olefin: Mechanistic and synthetic perspectives

Upon PET reaction, amines of type 1 undergo efficient cyclisations to produce pyrrolidines and piperidines. Mechanistically, involvement of delocalised α-silylmethyl amine radical cation as reactive intermediate in such cyclisations are described.