127526-86-7

Basic information

• Product Name: 1-[(benzoyloxy)amino]-2-nitrobenzene
• Synonyms: 1-[(benzoyloxy)amino]-2-nitrobenzene
• CAS NO: 127526-86-7
• Molecular Formula: C₁₃H₁₀N₂O₄
• Molecular Weight: 258.2295
• Mol File: 127526-86-7.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-[(benzoyloxy)amino]-2-nitrobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(benzoyloxy)amino]-2-nitrobenzene(127526-86-7)
• EPA Substance Registry System: 1-[(benzoyloxy)amino]-2-nitrobenzene(127526-86-7)

Safety Data

• Hazardous Substances Data: 127526-86-7(Hazardous Substances Data)

Upstream product

• 528-29-0 1,2-Dinitrobenzene 
• 19613-87-7 N-(2-nitrophenyl)hydroxylamine 
• 98-88-4 benzoyl chloride 

Downstream Products

• 480-96-6 benzofurazan oxide 
• 65-85-0 benzoic acid 
• 728-90-5 N-(2-nitrophenyl)benzanilide 
• 88-74-4 2-nitro-aniline 
• 5670-73-5 2,2'-dinitroazoxybenzene 

Relevant articles and documents

Reaction of N-Acyloxy-2-nitrobenzenamines.I. Thermolysis in Benzene or Bromobenzene

N-Acyloxy-2-nitro- and N-acyloxy-2,4-dinitro-benzenamines have been pyrolysed at 140 deg C in benzene or bromobenzene solution.Homolysis ( to form RCO2-radical and ArNH-radical) is ruled out since virtually all the carboxylate is isolated as carboxylic acid.This acid might arise via a concerted elimination process ( the other product being a benzofurazan 1-oxide), or via heterolysis to ArNH01+, RCO21- with subsequent transfer of proton, and cyclization of the singlet 2-nitrophenylnitrene.These simple reactions compete with bimolecular reactions of products with substrate, in which the corresponding amine, azoxy compound and acid anhydride are generated.Attempts to synthesize N-tosyloxy derivatives of nitrobenzenamines gave only thermal decomposition products.N-Trifluoroacetoxy-2,4-dinitrobenzenamine was isolated as a crude product which detonated violently.