127613-01-8

Basic information

• Product Name: (5',5')-bis-6-bromo-(-)-fisetinidol
• CAS NO: 127613-01-8
• Molecular Weight: 704.323
• Mol File: 127613-01-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (5',5')-bis-6-bromo-(-)-fisetinidol(CAS DataBase Reference)
• NIST Chemistry Reference: (5',5')-bis-6-bromo-(-)-fisetinidol(127613-01-8)
• EPA Substance Registry System: (5',5')-bis-6-bromo-(-)-fisetinidol(127613-01-8)

Safety Data

• Hazardous Substances Data: 127613-01-8(Hazardous Substances Data)

Upstream product

• 127612-93-5 6-Bromo-(-)-fisetinidol 
• 967-27-1 (+)-mollisacacidin 

Relevant articles and documents

Oligomeric Flavanoids. Part 8. The First Profisetinidins and Proguibourtinidins Based on C-8 Substituted (-)-Fisetinidol Units and Related c-ring Isomerized Analogues

Structural examination of the phenolic metabolites of Colophospermum mopane reveals the presence of the first profisetinidins and proguibourtinidins based on C-8 substituted (-)-fisetinidol units i.e. the (4α,8)-bis-(-)-fisetinidol (1), (+)-epifisetinidol-(4α,8)-(-)-fisetinidol (3), and the (+)-guibourtinidol-(4α,8)-(-)-fisetinidol (5).They are accompanied by the related functionalized tetrahydropyranochromenes (9), (11), (13), (15), and (17), and by a 2,4-diaryl-6-(2-benzopyranyl)chroman (19), the first C-ring isomerised analogue derived from a B-ring coupled profisetinidin.Efforts towards the synthesis of the (4,8)-bis-fisetinidols from 6-bromo-(-)-fisetinidol and the appropriate flavan-3,4-diol, lead to the biaryl type biflavanoids (33) and (35).Their genesis is explained in terms of an oxidative substitution reaction initiated by bromonium ion.