127680-77-7Relevant articles and documents
A Study of the Photochemically Induced Electron-Transfer Reactions Between Pyridinedicarbonitriles and Primary and Secondary Aliphatic Amines
Bernardi, Rosanna,Caronna, Tullio,Poggi, Gabriella,Vittimberga, Bruno M.
, p. 903 - 908 (2007/10/02)
A study on the photochemically induced electron-transfer from primary and secondary aliphatic amines as donors to pyridinecarbonitriles as the acceptor is reported.A comparison between the substitution positions and the spin density distributions, obtained via teoretical calculations using the 6-31+G basis set, shows some discrepancies, and forms the basis of a hypothesis on the mechanism of the reaction.