127717-10-6

Basic information

• Product Name: (2SR,3SR)-2,3-dimethyl-2-ethenylcyclohexanone
• Synonyms: (2SR,3SR)-2,3-dimethyl-2-ethenylcyclohexanone
• CAS NO: 127717-10-6
• Molecular Weight: 152.236
• Mol File: 127717-10-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2SR,3SR)-2,3-dimethyl-2-ethenylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2SR,3SR)-2,3-dimethyl-2-ethenylcyclohexanone(127717-10-6)
• EPA Substance Registry System: (2SR,3SR)-2,3-dimethyl-2-ethenylcyclohexanone(127717-10-6)

Safety Data

• Hazardous Substances Data: 127717-10-6(Hazardous Substances Data)

Upstream product

• 127891-14-9 (6R,7R)-6,7-Dimethyl-6-vinyl-1,4-dioxa-spiro[4.5]decane 
• 98361-28-5 2,3-dimethyl-1-trimethylsilyloxycyclohexene 
• 1066-54-2 trimethylsilylacetylene 
• 1121-18-2 2-methyl-2-cyclohexen-1-one 
• 100779-93-9 (+/-)-2-allyl-2,3-dimethylcyclohexanone 
• 127717-12-8 6-(2-hydroxyethyl)-6,7-dimethyl-1,4-dioxaspiro<4.5>-decane 
• 127716-99-8 (2R,3S)-2,3-Dimethyl-2-vinyl-cyclohexanol 
• 127891-14-9 (6R,7S)-6,7-Dimethyl-6-vinyl-1,4-dioxa-spiro[4.5]decane 
• 127717-12-8 6-(2-hydroxyethyl)-6,7-dimethyl-1,4-dioxaspiro<4.5>-decane 

Downstream Products

• 127716-99-8 (1R,2R,3R)-2,3-Dimethyl-2-vinyl-cyclohexanol 
• 127716-99-8 (1S,2R,3R)-2,3-Dimethyl-2-vinyl-cyclohexanol 
• 127716-99-8 (1R,2R,3S)-2,3-Dimethyl-2-vinyl-cyclohexanol 
• 127716-99-8 (1S,2R,3S)-2,3-Dimethyl-2-vinyl-cyclohexanol 
• 127891-10-5 (5R,6S)-6-But-3-ynyl-1,5,6-trimethyl-cyclohexene 
• 127891-07-0 (5R,6S)-6-(2-Iodo-ethyl)-1,5,6-trimethyl-cyclohexene 
• 127891-11-6 (5R,6S)-6-((E)-4-Iodo-3-methyl-but-3-enyl)-1,5,6-trimethyl-cyclohexene 
• 127891-16-1 (2R,3S)-2-(2-Benzyloxy-ethyl)-1,2,3-trimethyl-cyclohexanol 
• 127891-06-9 (2S,3R)-2-(2-Benzyloxy-ethyl)-2,3-dimethyl-cyclohexanone 
• 127891-27-4 (2E,6E)-3,7-Dimethyl-9-((1S,6R)-1,2,6-trimethyl-cyclohex-2-enyl)-nona-2,6-dien-1-ol 
• 126225-08-9 (5R,6S)-6-((3E,7E)-9-Bromo-3,7-dimethyl-nona-3,7-dienyl)-1,5,6-trimethyl-cyclohexene 
• 127891-15-0 (6R,7S)-6-(2-Benzyloxy-ethyl)-6,7-dimethyl-1,4-dioxa-spiro[4.5]decane 
• 88855-15-6 ageline A 

Relevant articles and documents

Equatorial preference in the GaCl3-promoted ethenylation of cyclic ketones

Silyl enol ethers derived from substituted cyclohexanones are ethenylated with trimethylsilylethyne in the presence of GaCl3. Carbon-carbon bond formation was completed in less than 5 min at room temperature and protodegallation of the organogallium intermediate formed with 6 M sulfuric acid gave β-enones. The reactions exhibit a bias for the equatorial C-C bond formation, which contrasts the axial stereochemistry of enolate alkylation. The origin of this stereoselectivity is discussed.

STEREOSELECTIVE CYCLIZATION OF (E)- AND (Z)-5,6-DIMETHYL-8-TRIMETHYLSILYL-6-OCTENALS

The diastereoselectivities in the acid-mediated cyclization of (E)- and (Z)-5,6-dimethyl-8-trimethylsilyl-6-octenals, both stereoselectively synthesized, were investigated.Excellent preference for the formation of cis-dimethylcyclohexanols was realized, s