127783-75-9

Basic information

• Product Name: 4'-CYANO[1,1'-BIPHENYL]-4-YL ACETATE
• Synonyms: 4'-CYANO[1,1'-BIPHENYL]-4-YL ACETATE
• CAS NO: 127783-75-9
• Molecular Formula: C₁₅H₁₁NO₂
• Molecular Weight: 237.25
• Mol File: 127783-75-9.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4'-CYANO[1,1'-BIPHENYL]-4-YL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-CYANO[1,1'-BIPHENYL]-4-YL ACETATE(127783-75-9)
• EPA Substance Registry System: 4'-CYANO[1,1'-BIPHENYL]-4-YL ACETATE(127783-75-9)

Safety Data

• Hazardous Substances Data: 127783-75-9(Hazardous Substances Data)

Upstream product

• 109233-63-8 4'-(carbonochloridoyl)-[1,1'-biphenyl]-4-yl acetate 
• 148-86-7 4-acetoxybiphenyl 
• 92-69-3 4-Phenylphenol 
• 84244-98-4 4'-bromobiphenyl-4-yl acetate 
• 33527-94-5 4-acetoxyiodobenzene 
• 131379-14-1 4-cyanophenylzinc bromide 
• 623-00-7 4-bromobenzenecarbonitrile 
• 19812-93-2 4-Cyano-4'-hydroxybiphenyl 
• 108-24-7 acetic anhydride 

Downstream Products

• 58743-78-5 4'-ethoxybiphenyl-4-carbonitrile 
• 58743-77-4 4'-methoxybiphenyl-4-carbonitrile 
• 52709-86-1 4-cyano-4'-propyloxybiphenyl 
• 52709-87-2 4'-butoxybiphenyl-4-carbonitrile 
• 52364-73-5 4-octyloxy-4'-cyanobiphenyl 
• 52364-72-4 4'-(heptyloxy)(1,1'-biphenyl)-4-carbonitrile 
• 41424-11-7 4'-(hexyloxy)-4-biphenylcarbonitrile 
• 52364-71-3 4'-(pentyloxy)-4-biphenylcarbonitrile 
• 58932-13-1 4-n-nonyloxy-4'-cyanobiphenyl 
• 19812-93-2 4-Cyano-4'-hydroxybiphenyl 

Relevant articles and documents

Synthetic method of 4-hydroxy-4'-biphenyl nitrile

The invention discloses a preparation method of 4-hydroxy-4'-biphenyl nitrile. The method comprises: reacting 4-hydroxybiphenyl (2) with acetyl chloride to generate 4-acetic acid biphenyl (3), reacting 4-acetic acid biphenyl (3) with oxalyl chloride under aluminium trichloride catalysis to generate 4-chlorocarbonyl-4'-acetic acid biphenyl (4), reacting 4-chlorocarbonyl-4'-acetic acid biphenyl (4)with ammonia water to generate 4-formamido-4'-acetic acid biphenyl (5), dehydrating 4-formamido-4'-acetic acid biphenyl (5) under phosphorus oxychloride catalysis to generate 4-cyano-4'-acetic acid biphenyl (6), and deacetylating 4-cyano-4'-acetic acid biphenyl (6) in the presence of sodium hydroxide to generate 4-hydroxy-4'-biphenyl nitrile (1). The method is simple in process, is economic and eco-friendly, and is suitable for industrial amplification requirement.

Palladium catalyzed cross-couplings of organozincs in ionic liquids

Negishi cross-coupling reactions between aryl- or benzylzinc halides and various aryl iodides smoothly occur in ionic liquids in the presence of the new ionic phosphine ligand 2. This solvent allows a facile work-up and rapid cross-coupling reactions at r

Process for the preparation of unsymmetric biaryl compounds

Unsymmetric biaryl compounds are prepared by coupling two different halogenoaromatics by reaction with a metal and carrying out the reaction in the presence of catalytic amounts of a nickel compound, a promoter and a phosphorus-containing ligand.