1280540-91-1Relevant articles and documents
Bis-Anthracene Fused Porphyrin as an Efficient Photocatalyst: Facile Synthesis and Visible-Light-Driven Oxidative Coupling of Amines
Droste, J?rn,Hansen, Michael Ryan,Klabunde, Sina,Mai, Yiyong,Yin, Yucheng,Yu, Chunyang,Zhang, Pengfei
, p. 16497 - 16503 (2020)
Development of high-performance photocatalysts for the conversion of amines is of great importance, but has remained a challenging task. Here, a bis-anthracene fused porphyrin (AFP) was synthesized in a high yield by a facile synthetic protocol, which involves a Suzuki coupling for the conjugation of two anthracene groups with a porphyrin ring, followed by oxidative cyclodehydrogenation. When serving as a photocatalyst, AFP exhibits an outstanding photocatalytic performance for the visible-light-induced aerobic oxidation of amines to imines at ambient conditions. Density functional theory calculations revealed that the low energy band gap, caused by the large planar and π-extended porphyrin structure of AFP, contributed to its high photocatalytic performance.
Seaweed-like 2D-2D Architecture of MoS2/rGO Composites for Enhanced Selective Aerobic Oxidative Coupling of Amines
Wang, Mingming,Wu, Haihong,Shen, Chaoren,Luo, Shuping,Wang, Dan,He, Lin,Xia, Chungu,Zhu, Gangli
, p. 1935 - 1942 (2019/03/21)
To provide a solution for pursuing high redox reactivity beyond the compromise between the numbers of sulfur vacancies and electron transfer ability, 2D-2D architecture of MoS2/rGO composite was fabricated with 2D graphene-like transition metal
