1282035-09-9

Basic information

• Product Name: W(3,5-dimethylphenylimide)2(chloride)2(dimethoxyethane)
• CAS NO: 1282035-09-9
• Molecular Weight: 583.211
• Mol File: 1282035-09-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: W(3,5-dimethylphenylimide)2(chloride)2(dimethoxyethane)(CAS DataBase Reference)
• NIST Chemistry Reference: W(3,5-dimethylphenylimide)2(chloride)2(dimethoxyethane)(1282035-09-9)
• EPA Substance Registry System: W(3,5-dimethylphenylimide)2(chloride)2(dimethoxyethane)(1282035-09-9)

Safety Data

• Hazardous Substances Data: 1282035-09-9(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 110-71-4 1,2-dimethoxyethane 
• 108-69-0 3,5-dimethylaminoaniline 
• 13520-76-8 tungsten dioxydichloride 

Relevant articles and documents

Room-temperature Z-selective homocoupling of α-olefins by tungsten catalysts

3,5-Dimethylphenylimido complexes of tungsten can be prepared using procedures analogous to those employed for other tungsten catalysts, as can bispyrrolide species and MonoAryloxide-Pyrrolide (MAP) species. Homocouplings of 1-hexene, 1-octene, and methyl 10-undecenoate are achieved in 45-89% yield and a Z selectivity of >99% with W(Nar″)(C3H6)(pyr) (OHIPT) as a catalyst. Homocoupling of terminal olefins in the presence of (E)-olefins elsewhere in the molecule also was achieved with excellent selectivity.