1282040-50-9Relevant articles and documents
A cerium(IV)-carbon multiple bond
Gregson, Matthew,Lu, Erli,McMaster, Jonathan,Lewis, William,Blake, Alexander J.,Liddle, Stephen T.
, p. 13016 - 13019 (2013)
Straightforward access to a cerium(IV)-carbene complex was provided by one-electron oxidation of an anionic ate cerium(III)-carbene precursor, thereby avoiding decomposition reactions that plague oxidations of neutral cerium(III) compounds. The cerium(IV)-carbene complex is the first lanthanide(IV)-element multiple bond and involves a twofold bonding interaction of two electron pairs between cerium and carbon. Copyright
Uranium-carbon multiple bonding: Facile access to the pentavalent uranium carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and comparison of UV=C and UIV=C bonds
Cooper, Oliver J.,Mills, David P.,McMaster, Jonathan,Moro, Fabrizio,Davies, E. Stephen,Lewis, William,Blake, Alexander J.,Liddle, Stephen T.
supporting information; experimental part, p. 2383 - 2386 (2011/04/21)
(Chemical Equation Presented) A straightforward oxidation strategy affords the first pentavalent uranium carbene complex, 2. Owing to the structural similarity of 1 and 2, it was possible for the first time to directly probe the differences in U=C bonding on oxidation of UIV to UV.