128300-30-1

Basic information

• Product Name: (S)-3-((R)-4-methylcyclohex-3-en-1-yl)butanal
• Synonyms: (S)-3-((R)-4-methylcyclohex-3-en-1-yl)butanal
• CAS NO: 128300-30-1
• Molecular Weight: 166.263
• Mol File: 128300-30-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (S)-3-((R)-4-methylcyclohex-3-en-1-yl)butanal(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-((R)-4-methylcyclohex-3-en-1-yl)butanal(128300-30-1)
• EPA Substance Registry System: (S)-3-((R)-4-methylcyclohex-3-en-1-yl)butanal(128300-30-1)

Safety Data

• Hazardous Substances Data: 128300-30-1(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 5989-27-5 D-limonene 
• 262290-94-8 (3S)-3-[(1R)-4-Methylcyclohex-3-enyl]butanol dinitrobenzoate ester 
• 73088-68-3 (1'R)-(2E)-3-methyl-3-(4'-methylcyclohexen-3'-yl)-propen-2-al-1 
• 15760-18-6 9-Hydroxy-methyl-Δ¹-p-menthen 
• 77614-31-4 (R)-3-(4-methyl-cyclohex-3-enyl)-but-3-enal 
• 262290-92-6 (S)-3-((R)-4-Methyl-cyclohex-3-enyl)-butan-1-ol 

Downstream Products

• 26462-78-2 (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde 
• 26091-09-8 (+)-Epitodomatuic acid 
• 26575-87-1 (+)-epijuvabione 
• 262290-97-1 (1R)-5-[(1S)-3-Hydroxy-1,5-dimethylhexyl]-2-methylenecyclohexanol 
• 262290-96-0 (2S)-2-[(1R)-4-Methylcyclohex-3-enyl]-6-methylheptan-4-ol 

Relevant articles and documents

Design and application of hybrid phosphorus ligands for enantioselective Rh-Catalyzed anti-markovnikov hydroformylation of unfunctionalized 1,1-disubstituted Alkenes

A series of novel hybrid phosphorus ligands were designed and applied to the Rh-catalyzed enantioselective anti-Markovnikov hydroformylation of unfunctionalized 1,1-disubstituted alkenes. By employing the new catalyst, linear aldehydes with β-chirality can be prepared with high yields and enantioselectivities under mild conditions. Furthermore, catalyst loading as low as 0.05 mol % furnished the desired product in good yield and undiminished selectivity, demonstrating the efficiency of this transformation in large-scale synthesis.

Baker's yeast mediated enantioselective synthesis of the bisabolene sesquiterpenes (+)-epijuvabione and (-)-juvabione

Fermenting baker's yeast converts the unsaturated aldehydes 7 and 11 into the saturated alcohols 8 and 12, respectively. The microbial saturation of the double bond proceeds in high chemical yields and the stereoselectivity of the reduction is strongly influenced by the E:Z ratio of the substrate. Enantiopure 8 and 12 are chiral building blocks for the synthesis of bisabolene sesquiterpenes and their usefulness is shown in the preparation of (+)-epijuvabione 1 and (-)-juvabione 3.