128496-94-6Relevant articles and documents
Improved synthesis of 2,3-dibromo-1-(phenylsulfonyl)-1-propene (DBP)
VanZanten, Aaron,Mullaugh, Katherine,Harrington, Ryan,Kiefer, Adam,Carlson, David,Mastarone, Dan,Lipchik, Corey,Murphree, S. Shaun
, p. 2611 - 2613 (2004)
A convenient preparation of 2,3-dibromo-1-(phenylsulfonyl)-1-propene (DBP, 1) is available through the one-pot propargylation and oxidation of thiophenol to give the propargyl sulfone 11, which is isomerized and brominated in another one-pot reaction. The
Tunable Regioselectivity Associated with the Reaction of 2,3-Dihalo-1-(phenylsulfonyl)-1-propenes with Ambident Nucleophilic Reagents
Padwa, Albert,Austin, David J.,Ishida, Masaru,Muller, Cheryl L.,Murphree, S. Shaun,Yeske, Philip E.
, p. 1161 - 1169 (2007/10/02)
2,3-Dihalo-1-(phenylsulfonyl)-1-propenes, obtained by the addition of bromine or iodine onto (phenylsulfonyl)propadiene, were found to exhibit interesting reactivity as both mono- and dielectrophiles, with the mode of reactivity depending upon the nature